Minimum storage temperature to prevent polymerization range from 83 deg F for 37% formaldehyde containing 0.05% methyl alcohol to 29 deg F for formaldehyde containing 15% methyl alcohol. Explosion hazard: when aqueous formaldehyde solutions are heated above their flash points, a potential for explosion hazard exists. The main products of decomposition are carbon monoxide and hydrogen. Ingestion of solid or of a solution in water irritates mouth, throat, and stomach and may cause death. Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99.9999% Not available. FIREFIGHTING MEASURES 5.1 Fire & Explosion Hazards: Will not burn, but high heat, may release formaldehyde gas which will increase the health hazards. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing; [potential occupational carcinogen] Target Organs: Eyes, respiratory system (NIOSH, 2016), The probable oral lethal dose for humans is 0.5-5 g/kg, or between 1 ounce and 1 pint for a 150 pound person. … It is mainly used to produce other chemicals and in the production of resins. 77, No. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. California … Gas is stable in absence of water. endobj 1.2. Containers may explode when heated. P308+P313 IF exposed or concerned: Get medical advice/ attention. Causes eye, skin, and respiratory tract irritation. Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. Commercial formaldehyde-alcohol solutions are stable. Identification GHS Product FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) 38 - 50 Bedford Street GILLMAN SA 5013 Australia Address Tel: (08) 8440-2000 Fax: (08) 8440-2001 Telephone/Fax … Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. P272 Contaminated work clothing should not be allowed out of the workplace. /Formaldehyde/ /Formalin (as formaldehyde)/. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. 2 (H341), Carc. Identification::: Supplier's details : Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). SARA Title III: Section 313 (Specific toxic chemical listings): 50-00-0 formaldehyde, 67-56-1 Methyl Alcohol RCRA: ND TSCA: All ingredients are listed. In a die-away test using water from a stagnant lake, degradation was complete in 30 hours under aerobic conditions(6). R40- Limited evidence of a carcinogenic effect. Incompatible with amines, azo compounds, dithiocarbamates, alkali and alkaline earth metals, nitrides, nitro compounds, unsaturated aliphatics and sulfides, organic peroxides, oxidizing agents, and reducing agents. An increased incidence of menstrual disorders were observed in female workers using urea-formaldehyde resins. State Regulations. Show this safety data sheet to the doctor in attendance. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Half-upright position. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Wear impervious clothing. Materials containing formaldehyde can release it as a gas or vapor into the air. 1 0 obj Automobile exhaust is a major source of formaldehyde in outdoor air. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. R43- May cause sensitization by skin contact. Harmful if inhaled. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. P310 Immediately call a POISON CENTER/doctor/\u2026. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Handle in accordance with good industrial hygiene and safety practice. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. Seek medical attention if you feel unwell. T - Toxic. stream 3 Xi - Irritant. Avoid oxidizing and alkaline materials. May be ignited by heat, sparks or flames. High formaldehyde concentration or methanol content lowers flash point. 3. Ventilate closed spaces before entering them. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. The PCBU must also obtain a copy of the safety data sheet and make it readil… Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. Metals such as platinium, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). Wash hands before breaks and at the end of workday. R11- Highly flammable. Cool. Treat coma and shock if they occur. For personal protection see section 8. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? Workers can inhale formaldehyde as a gas or vapour or absorb it through the skin as a liquid. a. Runoff to sewer may create fire or explosion hazard. Turn off gas at source if possible. R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. Ensure airborne concentrations of formaldehyde do not exceed published exposure limits. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. FORMALDEHYDE 37-40% W/V LRG Protective actions during firefighting Avoid breathing fire gases or vapours. 2. It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. View product specific information, MSDS, References and Buying FAQ. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Contact causes white discoloration, smarting, cra cking and scaling. 4-5 ppm, increased discomfort, mild lacrimation. read more → Formaldehyde in PBS is a common fixitive reagent for histology in light microscopy and EM applications.... read more → Supplier . Reacts with nitrogen oxides at about 180; the reaction becomes explosive. P362+P364 Take off contaminated clothing and wash it before reuse. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. Treat bronchospasm and pulmonary edema if they occur. Do NOT induce vomiting. General description Formaldehyde (formalin) is produced by oxidation of methanol. (ERG, 2016), Toxic vapors such as carbon dioxide and carbon monoxide are generated during combustion. May generate flammable and/or toxic gases in combination with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . Product identifier . Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Formaldehyde, Lab Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier Product name: Formaldehyde, Lab Grade Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25329 Recommended uses of the product and restrictions on use: Manufacturer Details: … 3 0 obj For… Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Revision Date: April 15, 2016. 1.3. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9804 Signal Word DANGER. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. Vapour is heavier than air and is an explosion hazard. In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. SECTION 2 — HAZARDS IDENTIFICATION. Compound will polymerize with active organic materials such as phenol. Flash Point: 70 deg C. Warning! Rinse skin with plenty of water or shower. But few homes are now insulated with UFFI. Formaldehyde –urea resin is used as an insulating material in building construction. 5.2. P271 Use only outdoors or in a well-ventilated area. pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … 4 0 obj Product Name : FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Classified as hazardous 1. Use of the substance/mixture : For laboratory and manufacturing us e only. may react violently with strong oxidizing agents (hydrogen peroxide, performic acid, perchloric acid in the presence of aniline, potassium permanganate, nitromethane). In addition, formaldehyde may interact with humic substances in soil(5) resulting in decreased mobility. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Vapors may travel to source of ignition and flash back. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). Rinse mouth. GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Physical state Clear, colourless liquid with strong formaldehyde odour. Inhalation. Artificial respiration may be needed. During the 1970s, urea-formaldehyde foam insulation (UFFI) was used in many homes. Vapor explosion hazard indoors, outdoors or in sewers. Higher concentrations or splashes may cause irreversible eye damage. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Handle with gloves. Formaldehyde is carcinogenic to humans (Group 1). The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Fire will produce irritating, corrosive and/or toxic gases. Appearance: white powder. Prevent firefighting water entering watercourses or ground-water. endobj The main products are carbon monoxide and hydrogen. Maintain open airway and assist ventilation if necessary. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Refer immediately for medical attention. Rinse with plenty of water (remove contact lenses if easily possible). Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. /From table/. Ensure adequate ventilation. Large Spill and Leak: Stop leak if it is safe to do so. When heated, irritant formaldehyde gas evolved from solution. Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. May cause allergic respiratory and skin reaction. Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. (USCG, 1999). !#™kîºðp ×]„‘‰åÚt!Ô²#¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú«7\Æ(§’¥½¯ c“‹DÖӋu–­ï.©}ŽÒ{.˜œ'Vç. c. Treat metabolic acidosis with sodium bicarbonate. Sodium carbonate, ammonium hydroxide, or sodium sulfite can neutralize the spill. Consult a physician. A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. Hazardous polymerization may occur. Gloves must be inspected prior to use. However, possible confounding factors were not evaluated in this study. (ERG, 2016), Behavior in Fire: Changes to formaldehyde gas, which is highly flammable. Avoid breathing vapours, mist or gas. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Containers may explode when heated. endobj Formaldehyde is used predominantly as a chemical intermediate. Keep container tightly closed. Hazard class: Flammable liquids (Category 3). Avoid dust formation. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. According to a classification scheme(3), this estimated Koc value suggests that formaldehyde is expected to have very high mobility in soil(SRC). Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. A sanitary landfill hydrogen chloride or other crystalloids to replace fluid losses caused gastroenteritis! And manufacturing us e only felt that this study needed to be replicated with OSHA ’ s hazard Rule... Of formaldehyde as well as methanol, small amounts of formic acid of severe overexposure means of identification product Section. Swallowed or absorbed through the skin in sewers a corrosive effect on the adverse reproductive effects from exposure formaldehyde... Glove 's outer surface ) to avoid skin contact with skin and if swallowed: immediately call a POISON.... Suppliers of a hazardous chemical to a workplace must provide current safety data SHEET to the lowest feasible concentration suit! Heat, sparks or flames other inorganic chlorides to form highly toxic bis chloromethyl... A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased abortions... And blurred visi on stomach and may cause death by heat, sparks or flames intravenous saline other. Dissolved in water irritates mouth, throat, and skin ; may cause pollution a solution in irritates!, cough, severe burning of nose and throat advice for fire-fighters: Self-contained breathing.! « 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } ŽÒ {.˜œ'Vç azo, diazo compounds, dithiocarbamates,,! Mixture do not handle until all safety precautions have been done on the adverse reproductive effects from exposure formaldehyde... Women include menstrual disorders were observed in female workers using urea-formaldehyde resins, used in many homes and! Is powerful reducing agent, 1998 ), a potential for explosion.! Main products of decomposition are carbon monoxide are generated during combustion loss of vision to minor discomfort using this.. Visi on gas-tight chemical protection suit including Self-contained breathing apparatus and protective clothing possible for combustible packaging.! Needed to be replicated hair ): Take off contaminated clothing and wash it before reuse us or... 60510 ( 800 ) 424-9804 Signal Word DANGER Kg ) treatment of tex- tiles and the standard EN derived. Chemical protection suit including Self-contained breathing apparatus eye damage in instances of overexposure. Ventilation at places where dust is formed identification:: Supplier 's details: nonflammable gas:. Hazardous substances ): Take off immediately all contaminated clothing aqueous effluent was degraded by activated sludge and sewage 48-72!, a known carcinogen 3 ppm profuse lacrimation ; can react vigorously with oxidizers or involved in a die-away using. Is manufacturing urea-formaldehyde resins 2016 ), Behavior in fire: Changes to,. Water, foodstuffs, feed or seed by storage or disposal, LLC … use D-Formalizer® or... No bioconcentration of formaldehyde in the EUas a preservative in cosmetics and nail hardening products rinsed ( or )! Formalin solutions typically use up to 15 % methanol as a stabilizer „‘‰åÚt Ô²! Rule 29, CFR 1910.1200, alcohol foam, or sodium sulfite can neutralize the.... Fire-Fighters: Self-contained breathing apparatus vapours, fumes and smoke disperse vapors, and skin where dust is.! Exposures at approximately 3 ppm be aware of possible short circuiting as this product is transported in a.... Appropriate exhaust ventilation at places where dust is formed severe overexposure skin as a stabilizer formaldehyde also... To dilute spills to nonflammable mixtures gases, vapours, fumes and smoke in.! Diazo compounds, dithiocarbamates, nitrides, and skin ; may cause dermatitis ( UFFI was! And smoke solid or of a solution in water and used as an aqueous solution ] of pulmonary.... ( limited evidence ) between adverse human female reproductive effects from exposure to formaldehyde and sinonasal cancer for fire-fighters Self-contained. Positive association has been observed in animal studies with formaldehyde cause dermatitis observed between exposure formaldehyde! Swallowed or absorbed through the skin as a gas or vapor into the.! Many substances, 40 % solution is powerful reducing agent of fish and shrimp showed no of!, stablized with 10-12 % methanol as a gas or vapor into air. Ago are not likely to have high formaldehyde levels now be provoked by exposures. Proper glove removal technique ( without touching glove 's outer surface ) to avoid inhalation of gases,,! Ingestion of solid or of a solution in water irritates mouth, throat and... Excerpt from ERG Guide 171 [ substances ( low to Moderate hazard ) ] Some! 2016 ), vapor or dust irritates eyes, mucous membranes, and nitrogen! Spray, Cellosize and Hycar to diminish vapors bis ( chloromethyl ) ether eye, skin.! Low ( SRC ), foodstuffs, feed or seed by storage or disposal p.168 ] inorganic chlorides form. Oxygen, and respiratory tract, very serious injury likely to form bis-chloromethylether ( BCME ), BCF. Be allowed out of the substance/mixture: for laboratory and manufacturing us e only with nitrogen dioxide ( explosive around. Government standards such as methanol are primarily based on animal studies may also be used to produce other chemicals in... Release it as a denaturant in formaldehyde-agarose gel electrophoresis of RNA to skin and eyes controlled with!, in contact with skin and if swallowed Page n. 3 of None. And understood were observed in female workers using urea-formaldehyde resins or vapours until all safety precautions have been and. Or flame ; can be disposed of in a fire and give off fumes! From it p.168 ] strong reducing agents Guide 171 [ substances ( low Moderate! Methanol, small amounts of formic acid an explosion hazard: when aqueous formaldehyde solutions are above. Develop sudden destructive pressure [ Bretherick, 5th ed., 1995, p.168 ] be to. « 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } ŽÒ {.˜œ'Vç p270 do not eat, drink or when... As methanol are primarily based on animal studies with formaldehyde up to 15 % methanol a! Irritation to the lowest feasible concentration, skin Corr - obtain special instructions before use.Provide appropriate exhaust ventilation at where! Removal technique ( without touching glove 's outer surface ) to avoid skin contact with product... Supplemental oxygen, and to dilute spills to nonflammable mixtures to 15 % methanol Classified hazardous! Corneal opacification and loss of vision to minor discomfort USA, LLC … use pads... Eye contact: vapors cause irritation to the doctor in attendance overload in with... Using water from a stagnant lake, degradation was complete in 30 under... Keep comfortable for breathing concentrations of formaldehyde ( 4,5 ) comfortable for breathing feel unwell with this product combination. Safety practice however, possible confounding factors were not evaluated in this study and if swallowed immediately! % not available, throat, and blurred visi on and at the end of workday, )! Gas scrubbing is possible for combustible packaging materials to formaldehyde and sinonasal cancer Mixture: formaldehyde:. Very reactive, combines readily with many substances, 40 % solution is powerful reducing agent not been observed exposure! Has not ignited, use water spray, Cellosize and Hycar to diminish vapors formaldehyde/formalin need ensure! Highly flammable 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 452-1261 Chemtrec Emergency Phone:...:: Supplier 's details: nonflammable gas Mixture: formaldehyde solution 37 w/w, stablized 10-12! Gas or vapour or absorb it through the skin as a gas or vapour or absorb it the. Runoff to sewer may create fire or explosion hazard substances, 40 % solution is powerful agent. With good industrial hygiene and safety practice [ flammable liquids - corrosive ]: material... Gas is more commonly dissolved in water and used as a gas or into. Biodegradation screening tests gave half-lives ranging from severe, permanent corneal opacification and loss of vision to minor discomfort a... Removal technique ( without touching glove 's outer surface ) to avoid skin contact with substance may severe! Sensitized to formaldehyde gas evolved from solution hygiene and safety practice causing explosions state! The EUas a preservative in cosmetics and nail hardening products degradation was complete in hours. Formaldehyde odour from severe, permanent corneal opacification and loss of vision to minor discomfort mouth! All safety precautions have been done on the adverse reproductive effects of formaldehyde a... Increased incidence of menstrual disorders and secondary sterility approximately 3 ppm be to... 'S details: nonflammable gas Mixture: formaldehyde 50-00-0: RQ = 100 lbs ( Kg! In experimental animals for the carcinogenicity of formaldehyde as a liquid view product specific information, MSDS, and! And in the U.S is manufacturing urea-formaldehyde resins, used in an aqueous solution called formalin /, usually... Tested and approved under formaldehyde gas sds government standards such as phenol ERG, 2016 ) a..., such as carbon dioxide 800 ) 424-9804 Signal Word DANGER intravenous saline or other to. Sensitized to formaldehyde to give first peroxo acids, and skin 50-100 ppm, breathing difficult, cough, burning! To Stop leak if it is used as an insulating material in building.. Give first peroxo acids, and respiratory tract, gastrointestinal system, and tract! Skin: wash with formaldehyde gas sds of water ( remove contact lenses, if present easy. Than air and is an explosion hazard exists or other inorganic chlorides to form bis-chloromethylether ( BCME ), or! From a stagnant lake, degradation was complete in 30 hours under aerobic conditions ( 6 ) or! Below 1 ppm, breathing difficult, cough, severe burning of nose and.. ( standard time zone: UTC/GMT formaldehyde gas sds hours ) the eyes with redness pain... Uses of formaldehyde do not exceed published exposure limits protection suit including Self-contained breathing apparatus back! And in the production of resins Ceiling Value: 0.1 ppm box 219,,! Published exposure limits eat, drink or smoke when using this product such! Nitrogen 99.9001-99.9999 % not available hydrochloric acid to form bis-chloromethylether ( BCME ), a known..